Electronegativity is the measure of an atom’s ability to attract shared electrons in a chemical bond. Factors influencing electronegativity include:
• Atomic size: Smaller atoms have higher electronegativity as the nucleus is closer to the bonding electrons.
• Nuclear charge: Higher positive charge in the nucleus increases the attraction for bonding electrons.
For example, fluorine is the most electronegative element due to its small size and high nuclear charge.
Consider the following compounds:
(i) CH₃CH₂Br
(ii) CH₃CH₂CH₂Br
(iii) CH₃CH₂CH₂CH₂Br
Arrange the compounds in the increasing order of their boiling points.