\(I=tan^{-1}\sqrt{\frac{1-x}{1+x}}\)
\(Let\space x=cosθ⇒dx=-sinθdθ\)
\(I=\int tan^{-1}\sqrt{\frac{1-cosθ}{1+cosθ}}(-sinθdθ)\)
\(=-\int tan^{-1}\sqrt{\frac{2sin^{2}\frac{θ}{2}}{2cos^{2}\frac{θ}{2}}}sinθdθ\)
\(=-\int tan^{-1}tan\frac{θ}{2}.sinθdθ\)
\(=-\frac{1}{2}∫θ.sinθdθ\)
\(=-\frac{1}{2}[θ.(-cosθ)-∫1.(-cosθ)dθ]\)
\(=-\frac{1}{2}[-θcosθ+sinθ]\)
\(=+\frac{1}{2}θcosθ-\frac{1}{2}sinθ\)
\(=\frac{1}{2}cos^{-1}x.x-\frac{1}{2}\sqrt{1-x^{2}}+C\)
\(=\frac{x}{2}cos^{-1}x-\frac{1}{2}\sqrt{1-x^{2}}+C\)
\(=\frac{1}{2}(xcos^{-1}x-\sqrt{1-x^{2}})+C\)
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.