Given below are two statements:
Statement I : Pure Aniline and other arylamines are usually colourless.
Statement II : Arylamines get coloured on storage due to atmospheric reduction.
Choose the correct answer
Given below are two statements:
Statement I : Pure Aniline and other arylamines are usually colourless.
Statement II : Arylamines get coloured on storage due to atmospheric reduction.
Choose the correct answer
Show Hint
Aniline turns brown on storage due to oxidation, not reduction, forming quinonoid structures.
- Both Statement I and Statement II are correct
- Statement I is incorrect but Statement II is correct
- Both Statement I and Statement II are incorrect
- Statement I is correct but Statement II is incorrect
The Correct Option is D
Solution and Explanation
Statement I: Pure aniline and other arylamines are indeed colourless liquids.
Statement II: Aniline becomes coloured on storage, not due to reduction, but due to oxidation by air and light, forming brown-coloured quinonoid compounds. Hence, Statement II is incorrect.
Top Questions on Amines
- Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is _____.
- Number of compounds which give reaction with Hinsberg's reagent is_______.
- An amine $(\text{X})$ is prepared by ammonolysis of benzyl chloride. On adding $p$-toluenesulphonyl chloride to it, the solution remains clear.Molar mass of the amine $(\text{X})$ formed is _____ $\text{g mol}^{-1}$.(Given molar mass in $\text{g mol}^{-1}$: $\text{C} = 12, \, \text{H} = 1, \, \text{O} = 16, \, \text{N} = 14$)
- X of enthanamine was subjected to reaction with \(NaNO_2/HCl\) followed by hydrolysis to liberate \(N_2\) and HCl. The HCl generated was completely neutralised by 0.2 moles of NaOH. X is ____ g.
- Given below are two statements:
Statement (I) : All the following compounds react with p-toluenesulfonyl chloride.
$C_6H_5NH_2 \quad (C_6H_5)_2NH \quad (C_6H_5)_3N$
Statement (II) : Their products in the above reaction are soluble in aqueous NaOH.
In the light of the above statements, choose the correct answer from the options given below.
Questions Asked in JEE Main exam
- A rectangular loop of length 2.5 m and width 2 m is placed at 60° to a magnetic field of 4 T. The loop is removed from the field in 10 sec. The average emf induced in the loop during this time is:
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- Two coils have mutual inductance 0.002 H. The current changes in the first coil according to the relation \( i = i_0 \sin \omega t \), where \( i_0 = 5 \, \text{A} \) and \( \omega = 50\pi \, \text{rad/s} \). The maximum value of emf in the second coil is \( \frac{\pi}{\alpha} \). The value of \( \alpha \) is ______.
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- Electromagnetic induction
- The 20th term from the end of the progression \[ 20, 19, \frac{1}{4}, \frac{1}{2}, \frac{3}{4}, \ldots, -129 \frac{1}{4} \] is:
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- Arithmetic Progression
- We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M, 0.01M & 0.001 M, respectively. The value of vant’ Haft factor (i) for these solutions will be in the order.
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- Colligative Properties
- $\Delta_{vap}H^\circ$ for water is $+40.49 \, \text{kJ mol}^{-1}$ at 1 bar and $100^\circ\text{C}$. Change in internal energy for this vaporisation under same condition is .............. kJ mol$^{-1}$. (Integer answer)
(Given R = 8.3 J K$^{-1}$ mol$^{-1}$)- JEE Main - 2024
- Enthalpy change
Concepts Used:
Amines
Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.
Amine - Types
Primary Amines:
It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.
Secondary Amines:
Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.
Tertiary Amines:
Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.