Question

Sodium salt of $\alpha$-halogen carboxylic acid when heated with sodium nitrite and followed by hydrolysis forms

• A. nitroalkane
• B. amine
• C. alcohol
• D. amide

Hint:

$\alpha$-Halogen carboxylic acids form nitroalkanes when treated with sodium nitrite followed by hydrolysis.

Answer 1

The Correct Option is A

Step 1: Reaction with sodium nitrite.
Sodium salt of $\alpha$-halogen carboxylic acid reacts with sodium nitrite to undergo nucleophilic substitution, replacing the halogen atom with a nitro group.

Step 2: Hydrolysis step.
On hydrolysis, the intermediate compound rearranges to form a nitroalkane.

Step 3: Elimination of other options.
This reaction does not produce amines, alcohols, or amides under the given conditions.

Step 4: Conclusion.
Therefore, the final product obtained is nitroalkane.