Step 1: For compounding semi-annually, the effective annual rate \( r_{{eff}} \) is calculated using the formula: \[ r_{{eff}} = \left(1 + \frac{r}{n}\right)^n - 1, \] where: - \( r \) is the nominal annual interest rate, - \( n \) is the number of compounding periods per year.
Step 2: Substitute the given values \( r = 0.10 \) (10%) and \( n = 2 \): \[ r_{{eff}} = \left(1 + \frac{0.10}{2}\right)^2 - 1 = (1.05)^2 - 1. \]
Step 3: Compute the value: \[ r_{{eff}} = 1.1025 - 1 = 0.1025 \quad {or} \quad 10.25\%. \]
| List-I | List-II |
| (A) Absolute maximum value | (I) 3 |
| (B) Absolute minimum value | (II) 0 |
| (C) Point of maxima | (III) -5 |
| (D) Point of minima | (IV) 4 |

Reactant ‘A’ underwent a decomposition reaction. The concentration of ‘A’ was measured periodically and recorded in the table given below:
Based on the above data, predict the order of the reaction and write the expression for the rate law.