Reaction of formaldehyde and ammonia gives
- Hexamethylene tetramine
- Bakelite
- Urea
- Triethylene Tetramine
The Correct Option is A
Solution and Explanation
$6 HCHO +4 NH _{3} \longrightarrow$
Top Questions on Preparation of Amines
- Which of the following compound will not undergo Azo coupling reaction?
- CUET (UG) - 2023
- Chemistry
- Preparation of Amines
- The product formed from the following reaction sequence is
- NEET (UG) - 2022
- Chemistry
- Preparation of Amines
Statement I: Primary aliphatic amines react with HNO2 to give unstable diazonium salts.
Statement II: Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K.
Choose the most appropriate answer from the options given below:- NEET (UG) - 2022
- Chemistry
- Preparation of Amines
- Which of the following reaction/s will not give \(p-\) aminoazobenzene?
- JEE Main - 2021
- Chemistry
- Preparation of Amines
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R
Assertion : tert-Butyl amine can be formed by Gabriel phthalimide synthesis.Reason : It follows \(SN_1\) mechanism.
In the light of the above statements, choose the correct answer from the options given below
- AIIMS - 2019
- Chemistry
- Preparation of Amines
Questions Asked in WBJEE exam
- A force \( \mathbf{F} = ai + bj + ck \) is acting on a body of mass \( m \). The body was initially at rest at the origin. The co-ordinates of the body after time \( t \) will be:
- WBJEE - 2025
- Newtons Laws of Motion
A quantity \( X \) is given by: \[ X = \frac{\epsilon_0 L \Delta V}{\Delta t} \] where:
- \( \epsilon_0 \) is the permittivity of free space,
- \( L \) is the length,
- \( \Delta V \) is the potential difference,
- \( \Delta t \) is the time interval.
The dimension of \( X \) is the same as that of:- WBJEE - 2025
- Dimensional Analysis
- Ruma reached the metro station and found that the escalator was not working. She walked up the stationary escalator with velocity \( v_1 \) in time \( t_1 \). On another day, if she remains stationary on the escalator moving with velocity \( v_2 \), the escalator takes her up in time \( t_2 \). The time taken by her to walk up with velocity \( v_1 \) on the moving escalator will be:
- WBJEE - 2025
- Relative Motion
- Which logic gate is represented by the following combination of logic gates?
- WBJEE - 2025
- Logic gates
- If \( {}^9P_3 + 5 \cdot {}^9P_4 = {}^{10}P_r \), then the value of \( 'r' \) is:
- WBJEE - 2025
- permutations and combinations
Concepts Used:
Preparation of Amines
- Reduction of nitro compounds: Nitro compounds are reduced to amines by reduction with metals in an acidic medium or by passing them through hydrogen gas in the presence of finely divided nickel, palladium, or platinum.
- Ammonolysis of alkyl halides: Alkyl benzyl halide undergoes a nucleophilic substitution reaction while reacting with an ethanolic solution of ammonia where the halogen atom is replaced by an amino group and this process of splitting of the C-X bond by an ammonia molecule is called ammonolysis.
- Reduction of Nitriles: On reduction of nitriles with lithium or aluminum hydride or catalytic hydrogenation are used.
- Reduction of amides: On reduction, the amides with lithium aluminum hydride yield amines.
- Gabriel phthalimide synthesis: Gabriel synthesis is used to prepare primary amines. Phthalimidewhen treated with ethanolic potassium hydroxide, forms potassium salt of phthalimide which when heated with alkyl halide followed by alkaline hydrolysis leads to the formation of the corresponding primary amine.
- Hoffmann bromamide degradation reaction: In the Hoffmann bromamide degradation reaction, the transfer of an alkyl or aryl group takes place from the carbonyl carbon of the amide to the nitrogen atom. The amine so formed, therefore, contains one carbon less than that present in the initial amine.