In the process of fertilization in angiosperms, the pollen tube releases male gametes into the ovule where two fusion events take place: syngamy (fusion of male and female gametes) and triple fusion (fusion of the second male gamete with the two polar nuclei, forming the triploid endosperm nucleus).
Step 1: Analyzing the options.
- Endosperm develops into seed (Option 1): This statement is incorrect. The endosperm develops into the nutritive tissue that nourishes the developing embryo, not into the seed itself. The seed consists of the embryo, seed coat, and endosperm (nutritive tissue).
- Ovary develops into fruit (Option 2): This is correct. After fertilization, the ovary develops into a fruit that encloses the seeds.
- Ploidy of PEN is 3n (Option 3): This is correct. The ploidy of the primary endosperm nucleus (PEN) is triploid (3n), as it is formed by the fusion of one male gamete with the two polar nuclei.
- Syngamy is the fusion of male and female gametes (Option 4): This is correct. Syngamy refers to the fusion of the male and female gametes, resulting in the formation of a diploid zygote.
Step 2: Conclusion.
The statement that endosperm develops into seed is incorrect. Endosperm develops into nutritive tissue, not the seed itself.
Final Answer:
\[
\boxed{\text{The correct answer is (1) Endosperm develops into seed.}}
\]