“PARAGRAPH II” A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction with an excess of Sn/HCl gives a major product, which on treatment with an excess of NaNO2/HCl at 0oC provides P as the product. P, upon treatment with excess of H2O at room temperature, gives the product Q. Bromination of Q in aqueous medium furnishes the product R. The compound P upon treatment with an excess of phenol under basic conditions gives the product S. The molar mass difference between compounds Q and R is 474 g mol–1 and between compounds P and S is 172.5 g mol–1. The total number of carbon atoms and heteroatoms present in one molecule of S is ______ .
[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5 Atoms other than C and H are considered as heteroatoms]
[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5 Atoms other than C and H are considered as heteroatoms]
Solution and Explanation
Number of Carbon atoms + Number of Heteroatoms = 51
Top Questions on Organic Chemistry
- Match the following and choose the correct option.
- JEE Main - 2026
- Chemistry
- Organic Chemistry
- Which of the following is the correct order of the reactivity of given nucleophiles when treated with \( \text{CH}_3\text{Br} \) in methanol? \( \text{F}^- \), \( \text{I}^- \), \( \text{C}_2\text{H}_5\text{O}^- \), \( \text{C}_6\text{H}_5\text{O}^- \)
- JEE Main - 2026
- Chemistry
- Organic Chemistry
- In the following reaction sequence, identify compound \( (R) \).
- JEE Main - 2026
- Chemistry
- Organic Chemistry
- Reactivity of the following on the basis of \( S_\text{N}1 \) mechanism.
- JEE Main - 2026
- Chemistry
- Organic Chemistry
- Consider the following sequence of reactions and identify \( A \), \( B \), and \( C \) respectively.
- JEE Main - 2026
- Chemistry
- Organic Chemistry
Questions Asked in JEE Advanced exam
- Let $ x_0 $ be the real number such that $ e^{x_0} + x_0 = 0 $. For a given real number $ \alpha $, define $$ g(x) = \frac{3xe^x + 3x - \alpha e^x - \alpha x}{3(e^x + 1)} $$ for all real numbers $ x $. Then which one of the following statements is TRUE?
- JEE Advanced - 2025
- Fundamental Theorem of Calculus
- A linear octasaccharide (molar mass = 1024 g mol$^{-1}$) on complete hydrolysis produces three monosaccharides: ribose, 2-deoxyribose and glucose. The amount of 2-deoxyribose formed is 58.26 % (w/w) of the total amount of the monosaccharides produced in the hydrolyzed products. The number of ribose unit(s) present in one molecule of octasaccharide is _____.
Use: Molar mass (in g mol$^{-1}$): ribose = 150, 2-deoxyribose = 134, glucose = 180; Atomic mass (in amu): H = 1, O = 16- JEE Advanced - 2025
- Biomolecules
Let $ P(x_1, y_1) $ and $ Q(x_2, y_2) $ be two distinct points on the ellipse $$ \frac{x^2}{9} + \frac{y^2}{4} = 1 $$ such that $ y_1 > 0 $, and $ y_2 > 0 $. Let $ C $ denote the circle $ x^2 + y^2 = 9 $, and $ M $ be the point $ (3, 0) $. Suppose the line $ x = x_1 $ intersects $ C $ at $ R $, and the line $ x = x_2 $ intersects $ C $ at $ S $, such that the $ y $-coordinates of $ R $ and $ S $ are positive. Let $ \angle ROM = \frac{\pi}{6} $ and $ \angle SOM = \frac{\pi}{3} $, where $ O $ denotes the origin $ (0, 0) $. Let $ |XY| $ denote the length of the line segment $ XY $. Then which of the following statements is (are) TRUE?
- JEE Advanced - 2025
- Conic sections
- Adsorption of phenol from its aqueous solution on to fly ash obeys Freundlich isotherm. At a given temperature, from 10 mg g$^{-1}$ and 16 mg g$^{-1}$ aqueous phenol solutions, the concentrations of adsorbed phenol are measured to be 4 mg g$^{-1}$ and 10 mg g$^{-1}$, respectively. At this temperature, the concentration (in mg g$^{-1}$) of adsorbed phenol from 20 mg g$^{-1}$ aqueous solution of phenol will be ____. Use: $\log_{10} 2 = 0.3$
- JEE Advanced - 2025
- Adsorption
- At 300 K, an ideal dilute solution of a macromolecule exerts osmotic pressure that is expressed in terms of the height (h) of the solution (density = 1.00 g cm$^{-3}$) where h is equal to 2.00 cm. If the concentration of the dilute solution of the macromolecule is 2.00 g dm$^{-3}$, the molar mass of the macromolecule is calculated to be $X \times 10^{4}$ g mol$^{-1}$. The value of $X$ is ____. Use: Universal gas constant (R) = 8.3 J K$^{-1}$ mol$^{-1}$ and acceleration due to gravity (g) = 10 m s$^{-2}\}$
- JEE Advanced - 2025
- Colligative Properties
Concepts Used:
Organic Chemistry - Some Basic Principles and Techniques
Organic Chemistry is a subset of chemistry dealing with compounds of carbon. Therefore, we can say that Organic chemistry is the chemistry of carbon compounds and is 200-225 years old. Carbon forms bond with itself to form long chains of hydrocarbons, e.g.CH4, methane and CH3-CH3 ethane. Carbon has the ability to form carbon-carbon bonds quite elaborately. Polymers like polyethylene is a linear chain where hundreds of CH2 are linked together.
Read Also: Organic Compounds
Importance of Organic Chemistry:
Organic chemistry is applicable in a variety of areas including-
- Medicines: Example- Aspirin which is a headache medicine and Ibuprofen is a painkiller, both are organic compounds. Other examples include paracetamol.
- Food: Example- Starch which is a carbohydrate is an organic compound and a constituent of rice and other grains. It is the source of energy.
- Clothing: Example- Nylon, Polyester and Cotton are forms of organic compounds.
- Fuels: Examples- Gasoline, Petrol and Diesel are organic compounds used in the automobile industry at large.