Nitration of phenyl benzoate yields the product
The Correct Option is C
Solution and Explanation
It is an electrophilic aromatic substitution reaction. Because the $COO ^{-}$ acts as an electron withdrawing group to one phenyl group and a moderate electron donating group to the other phenyl group the nitration will occur on the phenyl group where $COO ^{-}$ is acting as an electron donating group. The major product of the nitration will have the $- NO _{2}$ in the para position because the ortho position is partially blocked by the large COPh group.
Top Questions on Amines
- Number of compounds which give reaction with Hinsberg's reagent is_______.
- An amine $(\text{X})$ is prepared by ammonolysis of benzyl chloride. On adding $p$-toluenesulphonyl chloride to it, the solution remains clear.Molar mass of the amine $(\text{X})$ formed is _____ $\text{g mol}^{-1}$.(Given molar mass in $\text{g mol}^{-1}$: $\text{C} = 12, \, \text{H} = 1, \, \text{O} = 16, \, \text{N} = 14$)
- X of enthanamine was subjected to reaction with \(NaNO_2/HCl\) followed by hydrolysis to liberate \(N_2\) and HCl. The HCl generated was completely neutralised by 0.2 moles of NaOH. X is ____ g.
- Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is _____.
- Given below are two statements:
Statement (I) : All the following compounds react with p-toluenesulfonyl chloride.
$C_6H_5NH_2 \quad (C_6H_5)_2NH \quad (C_6H_5)_3N$
Statement (II) : Their products in the above reaction are soluble in aqueous NaOH.
In the light of the above statements, choose the correct answer from the options given below.
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Concepts Used:
Amines
Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.
Amine - Types
Primary Amines:
It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.
Secondary Amines:
Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.
Tertiary Amines:
Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.