Question:

Native silver metal forms a water soluble complex with a dilute aqueous solution of $NaCN$ in the presence of

Updated On: Jun 14, 2022
  • nitrogen
  • oxygen
  • carbon dioxide
  • argon
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The Correct Option is B

Solution and Explanation

A water soluble complex with silver and dilute aqueous solution of NaCN is $Na[Ag(CN)_2)$ In the cyanide process, the native silver is crushed and treated with aqueous NaCN solution and aerated.
$4Ag+8NaCN+2H_2O+O_2\rightarrow 4Na[Ag(CN)_2]+4NaOH$
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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements