N moles of an ideal gas undergo a two-step process as shown in the figure. Let \( P, V, T \) denote the pressure, volume and temperature of the gas. The gas, initially at state-1 \( (P_1, V_1, T_1) \), undergoes an isochoric (constant volume) process to reach state-A, and then undergoes an isobaric (constant pressure) expansion to reach state-2 \( (P_2, V_2, T_2) \). For an ideal gas, \( C_P - C_V = NR \), where \( C_P \) and \( C_V \) are heat capacities at constant pressure and volume. The heat gained by the gas in the two-step process is given by

Step 1: Heat added during isochoric process.
At constant volume, the heat gained is
\[
Q_{\text{isochoric}} = C_V (T_A - T_1).
\]
Since state-A lies vertically below state-2 in the figure and the final temperature is \( T_2 \), we have \( T_A = T_2 \). Therefore,
\[
Q_{\text{isochoric}} = C_V (T_2 - T_1).
\]
Step 2: Heat added during isobaric process.
At constant pressure \( P_2 \), heat added is
\[
Q_{\text{isobaric}} = P_2 (V_2 - V_1).
\]
Step 3: Total heat added.
Adding both contributions gives
\[
Q = C_V (T_2 - T_1) + P_2 (V_2 - V_1).
\]
This matches option (A).
Final Answer: \( P_2 (V_2 - V_1) + C_V (T_2 - T_1) \)
An ideal monoatomic gas is contained inside a cylinder-piston assembly connected to a Hookean spring as shown in the figure. The piston is frictionless and massless. The spring constant is 10 kN/m. At the initial equilibrium state (shown in the figure), the spring is unstretched. The gas is expanded reversibly by adding 362.5 J of heat. At the final equilibrium state, the piston presses against the stoppers. Neglecting the heat loss to the surroundings, the final equilibrium temperature of the gas is __________ K (rounded off to the nearest integer).
The residence-time distribution (RTD) function of a reactor (in min$^{-1}$) is 
The mean residence time of the reactor is __________ min (rounded off to 2 decimal places).}
Ideal nonreacting gases A and B are contained inside a perfectly insulated chamber, separated by a thin partition, as shown in the figure. The partition is removed, and the two gases mix till final equilibrium is reached. The change in total entropy for the process is _________J/K (rounded off to 1 decimal place).
Given: Universal gas constant \( R = 8.314 \) J/(mol K), \( T_A = T_B = 273 \) K, \( P_A = P_B = 1 \) atm, \( V_B = 22.4 \) L, \( V_A = 3V_B \).
The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:
\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is __________ MPa (rounded off to 3 decimal places).