Step 1: Understanding the Concept:
This question requires matching essential mineral elements with their specific deficiency symptoms in plants.
Step 2: Detailed Explanation:
A. Calcium (Ca): Calcium is a structurally important component of the cell wall (as calcium pectate) and is relatively immobile within the plant. Therefore, deficiency symptoms appear first in young, growing tissues. A classic symptom is the necrosis (death) of young meristematic regions like root tips and young leaves. Thus, A matches with III.
B. Zinc (Zn): Zinc is required for the synthesis of auxin, a plant hormone that promotes cell elongation. Zinc deficiency leads to reduced auxin levels, causing stunted growth with short internodes, resulting in a rosette habit (leaves are clustered in a circular form). Thus, B matches with IV.
C. Manganese (Mn): Manganese is an activator for many enzymes and is essential for the water-splitting step in photosynthesis. Deficiency leads to interveinal chlorosis (yellowing between veins) and the development of necrotic spots. Thus, C matches with I.
D. Nickel (Ni): Nickel is a component of the enzyme urease, which is vital for metabolizing urea into ammonia. In the absence of nickel, urea can accumulate to toxic levels, leading to leaf tip necrosis. Thus, D matches with II.
Step 3: Final Answer:
The correct set of matches is A-III, B-IV, C-I, D-II, which corresponds to option (D).