Match the LIST-I with LIST-II
| LIST-I | LIST-II | ||
| A. | Boltzmann constant | I. | \( \text{ML}^2\text{T}^{-1} \) |
| B. | Coefficient of viscosity | II. | \( \text{MLT}^{-3}\text{K}^{-1} \) |
| C. | Planck's constant | III. | \( \text{ML}^2\text{T}^{-2}\text{K}^{-1} \) |
| D. | Thermal conductivity | IV. | \( \text{ML}^{-1}\text{T}^{-1} \) |
Choose the correct answer from the options given below :
Let's find the dimensions of each quantity in LIST-I.
A. Boltzmann constant (k): From the ideal gas law, \( PV = NkT \), where P is pressure
(\( \text{ML}^{-1}\text{T}^{-2} \)), V is volume (\( \text{L}^3 \)), N is the number of particles (dimensionless), k is the Boltzmann constant, and T is temperature (K).
So, \( k = \frac{PV}{NT} = \frac{(\text{ML}^{-1}\text{T}^{-2})(\text{L}^3)}{(1)(\text{K})} = \text{ML}^2\text{T}^{-2}\text{K}^{-1} \)
Thus, A matches with III.
B. Coefficient of viscosity (\( \eta \)): From viscous force \( F = 6\pi \eta r v \), where F is force (\( \text{MLT}^{-2} \)), r is radius (L), and v is velocity (\( \text{LT}^{-1} \)).
So, \( \eta = \frac{F}{6\pi r v} = \frac{\text{MLT}^{-2}}{(1)(\text{L})(\text{LT}^{-1})} = \frac{\text{MLT}^{-2}}{\text{L}^2\text{T}^{-1}} = \text{ML}^{-1}\text{T}^{-1} \)
Thus, B matches with IV.
C. Planck's constant (h): From the energy of a photon \( E = hf \), where E is energy (\( \text{ML}^2\text{T}^{-2} \)) and f is frequency (\( \text{T}^{-1} \)). So, \( h = \frac{E}{f} = \frac{\text{ML}^2\text{T}^{-2}}{\text{T}^{-1}} = \text{ML}^2\text{T}^{-1} \)
Thus, C matches with I.
D. Thermal conductivity (K): From the rate of heat flow \( \frac{dQ}{dt} = -KA \frac{dT}{dx} \), where \( \frac{dQ}{dt} \) is power (\( \text{ML}^2\text{T}^{-3} \)), A is area (\( \text{L}^2 \)), and \( \frac{dT}{dx} \) is temperature gradient (\( \text{KL}^{-1} \)).
So, \( K = \frac{(dQ/dt) dx}{A dT} = \frac{(\text{ML}^2\text{T}^{-3})(\text{L})}{(\text{L}^2)(\text{K})} = \frac{\text{ML}^3\text{T}^{-3}}{\text{L}^2\text{K}} = \text{MLT}^{-3}\text{K}^{-1} \)
Thus, D matches with II.
The correct matching is A-III, B-IV, C-I, D-II, which corresponds to option (A).
To solve this problem, we need to match the physical quantities in LIST-I with their correct dimensional formulas in LIST-II. Let's analyze each option step-by-step:
Based on the above analysis, the correct matching is:
This corresponds to the correct answer: A-III, B-IV, C-I, D-II. Therefore, the solution is validated by matching the physical quantities with their correct dimensional formulas.

Method used for separation of mixture of products (B and C) obtained in the following reaction is: 