Step 1: Imazethapyr.
Imazethapyr is an ALS (Acetolactate Synthase) inhibitor herbicide, disrupting branched-chain amino acid synthesis. Hence A → II.
Step 2: Glyphosate.
Glyphosate inhibits EPSP synthase (5-enolpyruvylshikimate-3-phosphate synthase), blocking aromatic amino acid synthesis. Hence B → III.
Step 3: Clodinafop-propargyl.
This herbicide inhibits Acetyl-CoA carboxylase (ACCase), preventing lipid biosynthesis. Hence C → IV.
Step 4: Atrazine.
Atrazine is a photosystem II inhibitor, interfering with electron transport in photosynthesis. Hence D → I.
Step 5: Conclusion.
The correct matching is A - II, B - III, C - IV, D - I.