Step 1: Understanding the Effects of Pollutants
- Lead (Pb>50 ppb): Liver damage, as lead toxicity affects major organs.
- Sulfate (\( SO_4^{2-}>500 \) ppm): Laxative effect, leading to digestive disturbances.
- Nitrate (\( NO_3^->50 \) ppm): Causes 'Blue baby' syndrome, where oxygen transport in infants is impaired.
- Fluoride (\( F^->2 \) ppm): Leads to brown mottling of teeth (dental fluorosis).
Conclusion
Thus, the correct answer is:
\[
A-IV, B-III, C-II, D-I
\]