Zone refining: This method is used for the purification of metals like indium (In) and gallium where impurities are swept by a molten zone. So, A → II.
Liquation: In this method, a low melting metal like tin (Sn) is separated from higher melting impurities. So, B → I.
Vapour phase refining: This technique refines metals like zirconium (Zr), using a volatile compound. So, C → IV.
Distillation: Metals like zinc (Zn) with low boiling points are purified by distillation. So, D → III.
Hence, the correct matching is:
A → II, B → I, C → IV, D → III