List-I (System) | List-II (Axial lengths and angles) |
---|---|
(A) Cubic | (I) \(a = b = c, \alpha = \beta = \gamma = 90^\circ\) |
(B) Tetragonal | (II) \(a = b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
(C) Orthorhombic | (III) \(a \neq b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
(D) Hexagonal | (IV) \(a = b \neq c, \alpha = \beta = 90^\circ, \gamma = 120^\circ\) |
Crystal systems are classified based on their axial lengths and angles:
• Cubic: All sides are equal, and all angles are 90°
• Tetragonal: Two sides are equal, one different, all angles 90°
• Orthorhombic: All sides unequal, all angles 90°
• Hexagonal: Two sides equal, one different, two angles 90° and one 120°
Therefore, the correct matching is: (A) - (I), (B) - (III), (C) - (II), (D) - (IV).
Assertion (A): The boiling points of alkyl halides decrease in the order: RI>RBr>RCl>RF. Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.
Arrange the following compounds in increasing order of their boiling points: \includegraphics[]{6a.png}
\includegraphics[]{6b.png}
\includegraphics[]{6c.png}
(a) Arrange the following compounds in increasing order of their boiling point: \[ \text{(CH}_3\text{)}_2\text{NH, CH}_3\text{CH}_2\text{NH}_2, \text{CH}_3\text{CH}_2\text{OH} \]