List-I (System) | List-II (Axial lengths and angles) |
---|---|
(A) Cubic | (I) \(a = b = c, \alpha = \beta = \gamma = 90^\circ\) |
(B) Tetragonal | (II) \(a = b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
(C) Orthorhombic | (III) \(a \neq b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
(D) Hexagonal | (IV) \(a = b \neq c, \alpha = \beta = 90^\circ, \gamma = 120^\circ\) |
Crystal systems are classified based on their axial lengths and angles:
• Cubic: All sides are equal, and all angles are 90°
• Tetragonal: Two sides are equal, one different, all angles 90°
• Orthorhombic: All sides unequal, all angles 90°
• Hexagonal: Two sides equal, one different, two angles 90° and one 120°
Therefore, the correct matching is: (A) - (I), (B) - (III), (C) - (II), (D) - (IV).
Give Reasons:
(I) \( \text{Ce}^{4+} \) in aqueous solution is a good oxidising agent.
(II) The actinoid contraction is greater from element to element than lanthanoid contraction.
(III) \( E^\circ_{\text{M}^{2+}/\text{M}} \) value is more negative than expected, whereas \( E^\circ_{\text{Cu}^{2+}/\text{Cu}} \) is positive.