Step 1: The nuclear density \( \rho \) is given by: \[ \rho = \frac{{Mass}}{{Volume}} = \frac{A}{\frac{4}{3} \pi R^3} \] where \( A \) is the mass number, and \( R \) is the radius of the nucleus.
The radius of the nucleus is related to the mass number \( A \) by the empirical relation: \[ R \propto A^{1/3} \]
Step 2: Therefore, the density is given by: \[ \rho \propto \frac{A}{R^3} \propto \frac{A}{(A^{1/3})^3} = \frac{A}{A} = 1 \]
Step 3: Hence, the ratio of the nuclear densities of the two nuclei will be \( 1:1 \).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: