Question:

List-I contains various reaction sequences and List-II contains the possible products. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

List I

List II

(P)List-I contains various reaction sequences(1)
List-II contains the possible products
(Q)List-I contains various reaction sequences(2)
List-II contains the possible products
(R)List-I contains various reaction sequences(3)
List-II contains the possible products
(S)List-I contains various reaction sequences(4)
List-II contains the possible products
(5)
List-II contains the possible products

Updated On: Mar 7, 2025
  • P-3, Q-5, R-4, S-1
  • P-3, Q-2, R-4, S-1
  • P-3, Q-5, R-1, S-4
  • P-5, Q-2, R-4, S-1
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The Correct Option is A

Solution and Explanation

Step 1: Understanding the Reaction Sequences 

  • (P) Ozonolysis followed by base-induced rearrangement and protection
    • The reaction sequence cleaves a benzene ring, forming a six-membered hydroxy-containing ring.
    • Matches: (3)
  • (Q) Ozonolysis, protection, and hydroboration-oxidation
    • Leads to hydroxylation and the introduction of a methyl group.
    • Matches: (5)
  • (R) Hydration followed by reduction
    • Produces a hydroxy-substituted five-membered ring with a retained carbonyl group.
    • Matches: (4)
  • (S) Hydroboration-oxidation followed by reduction
    • Converts the five-membered ring into a hydroxyl-functionalized product.
    • Matches: (1)

Step 2: Conclusion

  • (P) → (3)
  • (Q) → (5)
  • (R) → (4)
  • (S) → (1)

Thus, the correct answer is (A) P-3, Q-5, R-4, S-1.

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