To solve this problem, we need to utilize the properties of an irrotational vector field. An irrotational vector field \( \vec{F} \) means that its curl is zero, i.e., \( \nabla \times \vec{F} = 0 \). According to Green's theorem, if \(\vec{F}\) is irrotational over the open surface \(S\) with boundary \(C\), then the line integral around the closed curve \(C\) is zero. Mathematically, this is expressed using the following: \[ \oint_C \vec{F} \cdot d\vec{R} = 0 \] Since \(\vec{F}\) is irrotational, there exists a scalar potential function \(\phi\) such that \(\vec{F} = \nabla \phi\). Therefore, substituting back, we have the line integral of the gradient: \[ \oint_C \vec{F} \cdot d\vec{R} = \oint_C (\nabla \phi) \cdot d\vec{R} = 0 \] This is because the line integral of a gradient over a closed path is zero, as it corresponds to the net change in the scalar field \(\phi\), and over a closed loop, that change is zero.
Hence, the correct answer is: \(\int_C (\text{grad } \phi) \cdot d\vec{R} = 0\), for some scalar function \(\phi\).