Let $ \bar{a}, \bar{b}, \bar{c} $ be three vectors such that $ \bar{a} $ is perpendicular to $ \bar{b} $ and $ \bar{b} $ is perpendicular to $ \bar{c} $. If $ |\bar{a}| = 2, |\bar{b}| = 3, |\bar{c}| = 5 $ and $ |\bar{a} + \bar{b} + \bar{c}| = 4\sqrt{3} $, then the angle between $ \bar{a} $ and $ \bar{c} $ is