Question:

Le-Chatelier's principle is not applicable to

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Le-Chatelier's principle is not applicable to pure solids and liquids because their concentrations do not change during chemical equilibrium.
Updated On: Feb 3, 2025
  • \({H}_2(g) + {I}_2(g) \rightleftharpoons 2 {HI}(g)\)
  • \({Fe}(s) + {S}(s) \rightleftharpoons {FeS}(s)\)
  • \({N}_2(g) + 3 {H}_2(g) \rightleftharpoons 2 {NH}_3(g)\)
  • \({N}_2(g) + {O}_2(g) \rightleftharpoons 2 {NO}(g)\)
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The Correct Option is B

Solution and Explanation

Le-Chatelier's principle applies to systems where changes in temperature, pressure, or concentration cause a shift in equilibrium. However, it does not apply to pure solids and liquids, because their concentrations do not change significantly during a reaction. 
Step 1: {Identifying the Pure Solids and Liquids} 
In reaction (B), Fe and S are pure solids, and thus, their concentrations do not significantly change during the reaction. Therefore, Le-Chatelier's principle is not applicable here. Thus, the correct answer is (B). 
 

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