Question:
In compounds of type $EC1_3$, where E = B , P, As or Bi, the angles Cl-E - Cl for different E are in the order
In compounds of type $EC1_3$, where E = B , P, As or Bi, the angles Cl-E - Cl for different E are in the order
Updated On: Jun 14, 2022
- B > P = As = Bi
- B > P > As > Bi
- B < P = As = Bi
- B < P < As < Bi
Hide Solution
Verified By Collegedunia
The Correct Option is B
Solution and Explanation
In BC13, bond angle = 120$^{\circ}$. In PC13, AsC13 and BiCl3, central atom is $sp^3$ hybridised. Since P, As and Bi are from the same group, bond angle decreases down the group. Hence, overall order of bond angle is : $ \, \, \, \, \, \, \, \, \, $ B > P > As > Bi
Was this answer helpful?
0
0
Top Questions on p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is:- JEE Main - 2024
- Chemistry
- p -Block Elements
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature.- JEE Main - 2024
- Chemistry
- p -Block Elements
- In which of the following species, the ratio of s-electrons to p-electrons is the same?
- TS EAMCET - 2024
- Chemistry
- p -Block Elements
The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- JEE Main - 2024
- Chemistry
- p -Block Elements
View More Questions
Questions Asked in JEE Advanced exam
- Let \(S=\left\{\begin{pmatrix} 0 & 1 & c \\ 1 & a & d\\ 1 & b & e \end{pmatrix}:a,b,c,d,e\in\left\{0,1\right\}\ \text{and} |A|\in \left\{-1,1\right\}\right\}\), where |A| denotes the determinant of A. Then the number of elements in S is _______.
- JEE Advanced - 2024
- Matrices
- A positive, singly ionized atom of mass number \( A_M \) is accelerated from rest by the voltage \( 192 \, \text{V} \). Thereafter, it enters a rectangular region of width \( w \) with magnetic field \( \vec{B}_0 = 0.1\hat{k} \, \text{T} \). The ion finally hits a detector at the distance \( x \) below its starting trajectory. Which of the following option(s) is(are) correct? \[ \text{(Given: Mass of neutron/proton = } \frac{5}{3} \times 10^{-27} \, \text{kg, charge of the electron = } 1.6 \times 10^{-19} \, \text{C).} \]
- JEE Advanced - 2024
- Electromagnetic Field (EMF)
- A thin stiff insulated metal wire is bent into a circular loop with its two ends extending tangentially from the same point of the loop. The wire loop has mass \( m \) and radius \( r \) and is in a uniform vertical magnetic field \( B_0 \). When a current \( I \) is passed through the loop, the loop turns about the line PQ by an angle \( \theta \). The angle \( \theta \) is given by:
- JEE Advanced - 2024
- Electromagnetic Field (EMF)
- A region in the form of an equilateral triangle (in x-y plane) of height \( L \) has a uniform magnetic field \( \mathbf{B} \) pointing in the \( +z \)-direction. A conducting loop PQR, in the form of an equilateral triangle of the same height \( L \), is placed in the x-y plane with its vertex \( P \) at \( x = 0 \) in the orientation shown in the figure. At \( t = 0 \), the loop starts entering the region of the magnetic field with a uniform velocity \( \mathbf{v} \) along the \( +x \)-direction. The plane of the loop and its orientation remain unchanged throughout its motion.
Which of the following graphs best depicts the variation of the induced emf (\( \mathcal{E} \)) in the loop as a function of the distance (\( x \)) starting from \( x = 0 \)?- JEE Advanced - 2024
- Radioactivity
- A table tennis ball has radius \( \frac{3}{2} \times 10^{-2} \, \text{m} \) and mass \( \frac{22}{7} \times 10^{-3} \, \text{kg} \). It is slowly pushed down into a swimming pool to a depth \( d = 0.7 \, \text{m} \) below the water surface and then released from rest. It emerges from the water surface at speed \( v \), without getting wet, and rises to a height \( H \). Which of the following option(s) is(are) correct?\(\text{(Given: } \pi = \frac{22}{7}, g = 10 \, \text{m/s}^2, \text{density of water} = 1 \times 10^3 \, \text{kg/m}^3, \text{viscosity of water} = 1 \times 10^{-3} \, \text{Pa.s).}\)
- JEE Advanced - 2024
- Radioactivity
View More Questions
Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family