The firing angle \( \alpha \) for a single-phase full converter can be calculated using the relation between the average and peak values of the output voltage. Using the formula:
\[
V_{avg} = \frac{V_{peak}}{\pi} \times (1 + \cos(\alpha))
\]
Given \( V_{avg} = 133V \) and \( V_{peak} = 325V \), solving the equation for \( \alpha \) gives:
\[
\alpha = 50^\circ
\]
Thus, the correct answer is 50 degrees.