The rate of decrease in the concentration of A is given by the change in concentration over time. The change in concentration \( \Delta [A] \) is: \[ \Delta [A] = [A]_{\text{initial}} - [A]_{\text{final}} = 0.4 \, \text{mol L}^{-1} - 0.1 \, \text{mol L}^{-1} = 0.3 \, \text{mol L}^{-1} \] The time interval is given as 20 minutes. Therefore, the rate of decrease in concentration is: \[ \text{Rate} = \frac{\Delta [A]}{\text{time}} = \frac{0.3 \, \text{mol L}^{-1}}{20 \, \text{min}} = 0.015 \, \text{mol L}^{-1} \text{min}^{-1} \] Thus, the rate of decrease in [A] is 0.015 mol L$^{-1}$ min$^{-1}$.
The correct option is (B) : \(0.015\)
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: