In a laser, population inversion is a condition where more electrons are in an excited state than in a lower energy state, enabling stimulated emission of photons. Why Between Two Closely Spaced Excited States?
In most practical lasers (like solid-state or gas lasers), population inversion is created between two excited states rather than between an excited state and the ground state.
Typically, electrons are pumped to a higher excited level and then quickly decay (non-radiatively) to a slightly lower metastable state.
From this metastable state, they transition to another excited state (not the ground state), emitting coherent photons.
This technique makes it easier to achieve and maintain population inversion.
Why Other Options Are Incorrect:
(A) Ground state is usually the most populated; achieving inversion with it is difficult.
(B) Vibrational levels apply to molecular transitions, not standard laser operation.
(D) While this might seem correct, the key phrase is “closely spaced” — which enables easier and faster transitions.
Hence, for effective laser operation, population inversion is typically achieved between two closely spaced excited states.