\( f \)
Using the Rydberg formula for the frequencies of lines in the hydrogen spectrum: \[ f = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] For a jump from the third excited state (n=4) to the first excited state (n=2), the frequency is: \[ f = R \left( \frac{1}{2^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{4} - \frac{1}{16} \right) = R \left( \frac{3}{16} \right) \] Comparing this with the frequency for the transition from the second orbit to the first, which is based on \( n_1 = 1, n_2 = 2 \), we find the ratio is \( \frac{1}{4} \).
Given below are two statements:
Statement (I): A spectral line will be observed for a \(2p_x \rightarrow 2p_y\) transition.
Statement (II): \(2p_x\) and \(2p_y\) are degenerate orbitals.
In the light of the above statements, choose the correct answer from the options given below:
Match the following: