Question:

If we assume that one-sixth the mass of an atom of 12C isotope is taken as the reference, the mass of one molecule of oxygen will:

Updated On: Jul 12, 2024
  • (A) Be double its original value
  • (B) Be half its original value
  • (C) Be the same
  • (D) Increase by four fold
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The Correct Option is C

Approach Solution - 1

Explanation:
If we assume that one-sixth the mass of an atom of 12C isotope is taken as the reference, the mass of one molecule of oxygen will be the same.We know that: 12 g of Carbon =6.023×1023 atomsSo, 1g=6.023×1023126g of carbon =6×6.023×102312=12×6.023×1023This is our new Avogadro's number according to the given conditions.Then, 1 atomic mass unit =1NA=26.023×1023Mass of 1 mole of O2=32× Avogrado's number ×26.023×1023=32×6.023×10232×26.023×1023=32gTherefore, there is no change in the mass number of O2.Hence, the correct option is (C).
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Approach Solution -2

Given:
One-sixth of the mass of a \(^{12}C\) atom is taken as the reference mass.

Reference mass:
Let \(m_{^{12}C}\) be the mass of one \(^{12}C\) atom.
Reference mass \(= \frac{1}{6} \times m_{^{12}C}\).

Mass of oxygen molecule O2:
The oxygen molecule O2 consists of 2 oxygen atoms.
Let \(m_{^{16}O}\) be the mass of one \(^{16}O\) atom.

The total mass of the O2 molecule:
 The total mass of the O2 molecule \(= 2 \times m_{^{16}O}\).

Since the reference mass is based on one-sixth of the mass of a \(^{12}C\) atom and does not affect the actual mass of oxygen atoms (assuming \(^{16}O\) isotopes), the mass of one molecule of oxygen O2 relative to this reference will be the same.

So, the correct answer is (C): be the same

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