We are given the vector equation:
\[
2\vec{a} + 3\vec{b} + 5\vec{c} - 10\vec{d} = 0.
\]
Rearrange the equation to solve for \( \vec{c} \):
\[
5\vec{c} = 10\vec{d} - 2\vec{a} - 3\vec{b}.
\]
Thus, we can express \( \vec{c} \) as a linear combination of \( \vec{a} \), \( \vec{b} \), and \( \vec{d} \), and the ratio in which the line joining \( \vec{c} \) divides the segment joining \( \vec{a} \) and \( \vec{b} \) can be found as:
\[
{Ratio} = 3:2.
\]
Thus, the correct answer is \( 3:2 \).