Step 1: Use properties of unit vectors.
Since both \( \vec{a} \) and \( \vec{b} \) are unit vectors:
\[
|\vec{a}| = 1, \quad |\vec{b}| = 1
\]
Additionally, we are given that \( (\vec{a}, \vec{b}) = 0 \), meaning the vectors are orthogonal (the angle \( \theta \) between them is \( 90^\circ \)).
Step 2: Compute \( |\vec{a} - \vec{b}| \).
The magnitude of the difference between the two vectors is:
\[
|\vec{a} - \vec{b}| = \sqrt{|\vec{a}|^2 + |\vec{b}|^2 - 2(\vec{a}, \vec{b})} = \sqrt{1^2 + 1^2 - 2(0)} = \sqrt{2}
\]
We are also given that \( |\vec{a} - \vec{b}| = 1 \), so this implies that:
\[
|\vec{a} + \vec{b}| = \sqrt{2}
\]
Step 3: Calculate the value of \( 2|\vec{a} + \vec{b}| \cos\theta \).
Since the vectors are orthogonal:
\[
\cos\theta = 0
\]
Thus, we have:
\[
2|\vec{a} + \vec{b}| \cos\theta = 3
\]