Step 1: Understanding Wave Interference
When two electromagnetic waves superimpose, their resultant electric field is given by:
\[
\vec{E} = \vec{E_1} + \vec{E_2}
\]
Given the wave equations:
\[
\vec{E_1} = E_0 \sin (kx - \omega t) \hat{j}
\]
\[
\vec{E_2} = E_0 \sin (kx - \omega t + \pi) \hat{j}
\]
Since \(\sin(\theta + \pi) = -\sin(\theta)\), we rewrite:
\[
E_2 = E_0 \sin (kx - \omega t + \pi) = -E_0 \sin (kx - \omega t)
\]
Step 2: Adding the Fields
\[
E_{\text{resultant}} = E_0 \sin (kx - \omega t) + (-E_0 \sin (kx - \omega t))
\]
\[
E_{\text{resultant}} = 0
\]
Thus, the resultant electric field is zero, meaning complete destructive interference has occurred.
Thus, the correct answer is \( \mathbf{(4)} \) Zero.