The position vector of the particle is given by:
\[
\mathbf{r}(t) = 3 \hat{i} + 2 t^2 \hat{j}
\]
To find the velocity, we differentiate the position vector with respect to time:
\[
\mathbf{v}(t) = \frac{d}{dt} \mathbf{r}(t)
\]
Differentiating each component:
\[
\mathbf{v}(t) = \frac{d}{dt} (3 \hat{i}) + \frac{d}{dt} (2 t^2 \hat{j})
\]
\[
\mathbf{v}(t) = 0 \hat{i} + 4 t \hat{j}
\]
Thus, the velocity vector is:
\[
\mathbf{v}(t) = 4 t \hat{j}
\]
At \( t = 5 \) seconds:
\[
\mathbf{v}(5) = 4 \times 5 \hat{j} = 20 \hat{j} \, {m/s}
\]
The magnitude of the velocity is:
\[
|\mathbf{v}(5)| = 20 \, {m/s}
\]
Thus, the magnitude of the velocity at \( t = 5 \) seconds is \( 20 \, {ms}^{-1} \).
\[
\boxed{20}
\]