The second hand of an analog clock completes one full revolution (\( 2\pi \) radians) in 60 seconds.
The angular velocity \( \omega \) is calculated as: \[ \omega = \frac{{\text{Total angle covered in radians}}}{{\text{Time taken}}} \] \[ \omega = \frac{2\pi}{60} = \frac{\pi}{30} \, \text{rad/s} \] Thus, the angular velocity of the second hand is \( \frac{\pi}{30} \) rad/s.
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: