The decay rate \( R(t) \) of a radioactive sample is given by the equation: \[ R(t) = R_0 e^{-\lambda t} \] where \( R_0 \) is the initial decay rate, \( \lambda \) is the decay constant, and \( t \) is the time. After one half-life \( T_{1/2} \), the decay rate is reduced by half.
Therefore, the decay rate after half-life is: \[ R(T_{1/2}) = \frac{R_0}{2} \] Thus, after one half-life, the decay rate of the sample is \( \frac{R_0}{2} \).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively:
\[ f(x) = \begin{cases} x\left( \frac{\pi}{2} + x \right), & \text{if } x \geq 0 \\ x\left( \frac{\pi}{2} - x \right), & \text{if } x < 0 \end{cases} \]
Then \( f'(-4) \) is equal to:If \( f'(x) = 4x\cos^2(x) \sin\left(\frac{x}{4}\right) \), then \( \lim_{x \to 0} \frac{f(\pi + x) - f(\pi)}{x} \) is equal to: