The total heat supplied in this process has two components:
1. The heat required to melt the ice at 0°C.
2. The heat required to increase the temperature of water from 0°C.
The heat required to melt the ice is given by the formula: \[ Q_{{melt}} = mL, \] where: - \( m = 1 \, {g} = 0.001 \, {kg} \) (mass of ice),
- \( L = 3.35 \times 10^5 \, {J/kg} \) (latent heat of fusion of ice).
So, the heat required to melt the ice is: \[ Q_{{melt}} = 0.001 \times 3.35 \times 10^5 = 335.0 \, {J}. \]
The total heat supplied is 418.72 J, and the heat required to melt the ice is 335 J.
Therefore, the remaining heat \( Q_{{water}} \) is used to increase the temperature of the water, which is: \[ Q_{{water}} = Q_{{total}} - Q_{{melt}} = 418.72 \, {J} - 335.0 \, {J} = 83.72 \, {J}. \] Thus, the quantity of heat used to increase the temperature of water from 0°C is 83.72 J, which corresponds to option (A).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: