We are given two curves:
\[
y^2 = 6x \quad \text{(1)}
\]
and
\[
9x^2 + by^2 = 16 \quad \text{(2)}.
\]
To find the value of \(b\), we first differentiate both equations with respect to \(x\).
From equation (1):
\[
2y \frac{dy}{dx} = 6 \quad \Rightarrow \quad \frac{dy}{dx} = \frac{3}{y}.
\]
From equation (2):
\[
18x + 2by \frac{dy}{dx} = 0 \quad \Rightarrow \quad \frac{dy}{dx} = -\frac{9x}{by}.
\]
For the curves to intersect at right angles, the product of the slopes of the tangents at the point of intersection must be \(-1\):
\[
\frac{3}{y} \cdot \left(-\frac{9x}{by}\right) = -1.
\]
Simplifying:
\[
-\frac{27x}{by^2} = -1 \quad \Rightarrow \quad \frac{27x}{by^2} = 1.
\]
Using equation (1), \(y^2 = 6x\), substitute this into the above equation:
\[
\frac{27x}{b \cdot 6x} = 1 \quad \Rightarrow \quad \frac{27}{6b} = 1 \quad \Rightarrow \quad b = \frac{9}{2}.
\]
Thus, the value of \(b\) is \(\frac{9}{2}\).