Step 1: The relationship between the tensions at the interfaces is governed by the forces acting at the point of contact. The tensions are related by the equilibrium condition at the solid-liquid interface. At the solid-liquid interface, the angle of contact \( \theta \) plays a crucial role in determining the relationship between the tensions. The forces acting along the surface are balanced, and the equation of equilibrium is given by: \[ S_1 \cos \theta + S_3 = S_2 \] where: - \( S_1 \) is the tension at the liquid-air interface, - \( S_2 \) is the tension at the solid-air interface, - \( S_3 \) is the tension at the solid-liquid interface, - \( \theta \) is the angle of contact at the solid-liquid interface.
Step 2: The above equation satisfies the condition for equilibrium, where the components of the tensions along the interface balance out. Therefore, the correct relation is: \[ S_1 \cos \theta + S_3 = S_2 \]