Step 1: Relate the Diagonal of the Cube to Its Side Length.
Let the side length of the cube be \( a \). The volume of the cube is:
\[
V = a^3.
\]
The length of the space diagonal of the cube is given by:
\[
\ell = a\sqrt{3}.
\]
Step 2: Express \( \ell \) in Terms of \( V \).
From \( V = a^3 \), we have:
\[
a = \sqrt[3]{V}.
\]
Substitute \( a = \sqrt[3]{V} \) into the expression for \( \ell \):
\[
\ell = \sqrt[3]{V} \cdot \sqrt{3}.
\]
Cube both sides to eliminate the cube root:
\[
\ell^3 = \left(\sqrt[3]{V} \cdot \sqrt{3}\right)^3 = \left(\sqrt[3]{V}\right)^3 \cdot \left(\sqrt{3}\right)^3 = V \cdot 3\sqrt{3}.
\]
Thus:
\[
3\sqrt{3} \, V = \ell^3.
\]
Step 3: Analyze the Options.
Option (1): \( 3V = \ell^3 \) — Incorrect, as it does not match the derived equation.
Option (2): \( \sqrt{3} V = \ell^3 \) — Incorrect, as it does not match the derived equation.
Option (3): \( 3\sqrt{3} V = 2\ell^3 \) — Incorrect, as it does not match the derived equation.
Option (4): \( 3\sqrt{3} V = \ell^3 \) — Correct, as it matches the derived equation.
Step 4: Final Answer.
\[
(4) \mathbf{3\sqrt{3} V = \ell^3}
\]