Step 1: We are given the equation \( \cos^{-1}(2x) + \cos^{-1}(3x) = \frac{\pi}{3} \). To simplify this, use the identity for the sum of inverse cosines: \[ \cos^{-1}(A) + \cos^{-1}(B) = \cos^{-1}(AB - \sqrt{(1-A^2)(1-B^2)}) \] Substituting \( A = 2x \) and \( B = 3x \): \[ \cos^{-1}(2x) + \cos^{-1}(3x) = \cos^{-1}\left( 2x \cdot 3x - \sqrt{(1 - (2x)^2)(1 - (3x)^2)} \right) \] We are told that this is equal to \( \frac{\pi}{3} \), so: \[ \cos^{-1}\left( 6x^2 - \sqrt{(1 - 4x^2)(1 - 9x^2)} \right) = \frac{\pi}{3} \] Taking the cosine of both sides, we get: \[ 6x^2 - \sqrt{(1 - 4x^2)(1 - 9x^2)} = \frac{1}{2} \] Step 2: Now, simplify the equation. First isolate the square root term: \[ \sqrt{(1 - 4x^2)(1 - 9x^2)} = 6x^2 - \frac{1}{2} \] Square both sides: \[ (1 - 4x^2)(1 - 9x^2) = \left( 6x^2 - \frac{1}{2} \right)^2 \] Expanding both sides: \[ (1 - 4x^2)(1 - 9x^2) = 1 - 9x^2 - 4x^2 + 36x^4 = 1 - 13x^2 + 36x^4 \] \[ \left( 6x^2 - \frac{1}{2} \right)^2 = 36x^4 - 6x^2 + \frac{1}{4} \] Equating both sides: \[ 1 - 13x^2 + 36x^4 = 36x^4 - 6x^2 + \frac{1}{4} \] Simplifying: \[ 1 - 13x^2 = -6x^2 + \frac{1}{4} \] \[ 1 - 13x^2 + 6x^2 = \frac{1}{4} \] \[ 1 - 7x^2 = \frac{1}{4} \] \[ 7x^2 = \frac{3}{4} \] \[ x^2 = \frac{3}{28} \] Step 3: Substitute this value of \( x^2 \) into the equation \( 4x^2 = \frac{a}{b} \): \[ 4x^2 = 4 \cdot \frac{3}{28} = \frac{12}{28} = \frac{3}{7} \] Thus, \( \frac{a}{b} = \frac{3}{7} \), so \( a = 3 \) and \( b = 7 \).
Step 4: Finally, calculate \( a + b \): \[ a + b = 3 + 7 = 10 \]
If the roots of $\sqrt{\frac{1 - y}{y}} + \sqrt{\frac{y}{1 - y}} = \frac{5}{2}$ are $\alpha$ and $\beta$ ($\beta > \alpha$) and the equation $(\alpha + \beta)x^4 - 25\alpha \beta x^2 + (\gamma + \beta - \alpha) = 0$ has real roots, then a possible value of $y$ is:
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))