If adenine is 31% in DNA, calculate the percentage of cytosine. Explain briefly.
Adenine pairs with thymine (31% each), totaling 62\%. Cytosine and guanine share the remaining 38%. Therefore, cytosine is 19%, following Chargaff’s rule, where purines (adenine, guanine) always pair with pyrimidines (thymine, cytosine).
(A) Explain the following reactions and write chemical equations involved:
(a) Wolff-Kishner reduction
(b) Etard reaction
(c) Cannizzaro reaction