Question:

If a particle's state function is an eigenfunction of the operator \( \hat{L}^2 \) with eigenvalue \( 30 \hbar^2 \), then the possible eigenvalue(s) of the operator \( \hat{L}_z \) for the same state function is/are

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The eigenvalues of \( \hat{L}^2 \) are \( l(l+1) \hbar^2 \), and the eigenvalues of \( \hat{L}_z \) are \( m_l \hbar \), where \( -l \le m_l \le l \). First, determine the value of \( l \) from the eigenvalue of \( \hat{L}^2 \). Then, find the possible values of \( m_l \) and the corresponding eigenvalues of \( \hat{L}_z \). If the options are in terms of \( \hat{L}_z^2 \), then consider \( m_l^2 \hbar^2 \).
Updated On: Apr 19, 2025
  • \( 10 \hbar^2 \)
  • \( 16 \hbar^2 \)
  • \( 25 \hbar^2 \)
  • \( 0 \)
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The Correct Option is B, C, D

Solution and Explanation

The operator ℒ² (denoted as ̂L2) is the square of the total angular momentum operator, and its eigenvalues are given by:

L2ψ = l(l + 1)ℐ2ψ

Here, l is the azimuthal quantum number: l = 0, 1, 2, ...

The z-component of angular momentum, ̂Lz, has eigenvalues:

Lzψ = mlℐψ

Where ml is the magnetic quantum number and ranges from −l to +l in integer steps.


Given: Eigenvalue of ̂L2 is 30ℐ2, so:

l(l + 1) = 30

Solving:

l² + l − 30 = 0 → (l + 6)(l − 5) = 0 → l = 5 (since l must be ≥ 0)

For l = 5, possible values of ml are:

−5, −4, −3, −2, −1, 0, 1, 2, 3, 4, 5

Thus, eigenvalues of Lz are:

mlℐ = −5ℐ, −4ℐ, ..., 0, ..., +5ℐ

If the question asks for possible values of Lz2, then we look at:

(mlℐ)2 = ml22 = 0, 1ℐ2, 4ℐ2, 9ℐ2, 16ℐ2, 25ℐ2

Comparison with options:

  • (A) 10ℐ2 → ❌ Not a perfect square
  • (B) 16ℐ2 → ✅ ml = ±4
  • (C) 25ℐ2 → ✅ ml = ±5
  • (D) 0 → ✅ ml = 0

Final Answer: The possible eigenvalues of Lz2 are: (B), (C), and (D).

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