If a particle's state function is an eigenfunction of the operator \( \hat{L}^2 \) with eigenvalue \( 30 \hbar^2 \), then the possible eigenvalue(s) of the operator \( \hat{L}_z \) for the same state function is/are
The operator ℒ² (denoted as ̂L2) is the square of the total angular momentum operator, and its eigenvalues are given by:
L2ψ = l(l + 1)ℐ2ψ
Here, l is the azimuthal quantum number: l = 0, 1, 2, ...
The z-component of angular momentum, ̂Lz, has eigenvalues:
Lzψ = mlℐψ
Where ml is the magnetic quantum number and ranges from −l to +l in integer steps.
Given: Eigenvalue of ̂L2 is 30ℐ2, so:
l(l + 1) = 30
Solving:
l² + l − 30 = 0 → (l + 6)(l − 5) = 0 → l = 5 (since l must be ≥ 0)
For l = 5, possible values of ml are:
−5, −4, −3, −2, −1, 0, 1, 2, 3, 4, 5
Thus, eigenvalues of Lz are:
mlℐ = −5ℐ, −4ℐ, ..., 0, ..., +5ℐ
If the question asks for possible values of Lz2, then we look at:
(mlℐ)2 = ml2ℐ2 = 0, 1ℐ2, 4ℐ2, 9ℐ2, 16ℐ2, 25ℐ2
Comparison with options:
Final Answer: The possible eigenvalues of Lz2 are: (B), (C), and (D).
The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below.
The slope of the line is \(0.36 \times 10^2\) s, and the y-intercept is \(1.20\) mol\(^{-1}\) L s. The value of the Michaelis constant (\(K_M\)) is ________ \( \times 10^{-3} \) mol L\(^{-1}\) (in integer). [Note: \(v\) is the initial rate, and \([S]_0\) is the substrate concentration]
Consider a Carnot engine with a hot source kept at 500 K. From the hot source, 100 J of energy (heat) is withdrawn at 500 K. The cold sink is kept at 300 K. The efficiency of the Carnot engine is ___________ (rounded off to one decimal place).
For the cell reaction, \[ Hg_2Cl_2 (s) + H_2 (1 \, {atm}) \rightarrow 2Hg (l) + 2H^+ (a=1) + 2Cl^- (a=1) \] The standard cell potential is \( \mathcal{E}^0 = 0.2676 \) V, and \( \left(\frac{\partial \mathcal{E}^0}{\partial T}\right)_P = -3.19 \times 10^{-4} \) V K\(^{-1}\). The standard enthalpy change of the reaction (\( \Delta_r H^0 \)) at 298 K is \( -x \) kJ mol\(^{-1}\). The value of \( x \) is ___________ (rounded off to two decimal places). [Given: Faraday constant \( F = 96500 \) C mol\(^{-1}\)]
The mean energy of a molecule having two available energy states at \( \epsilon = 0 \) J and \( \epsilon = 4.14 \times 10^{-21} \) J at 300 K is ___________ \( \times 10^{-21} \) J (rounded off to two decimal places). [Given: Boltzmann constant \( k_B = 1.38 \times 10^{-23} \) J K\(^{-1}\)]
Wavefunctions and energies for a particle confined in a cubic box are \( \psi_{n_x,n_y,n_z} \) and \( E_{n_x,n_y,n_z} \), respectively. The functions \( \phi_1, \phi_2, \phi_3 \), and \( \phi_4 \) are written as linear combinations of \( \psi_{n_x,n_y,n_z} \). Among these functions, the eigenfunction(s) of the Hamiltonian operator for this particle is/are \[ \phi_1 = \frac{1}{\sqrt{2}} \psi_{1,4,1} - \frac{1}{\sqrt{2}} \psi_{2,2,3} \] \[ \phi_2 = \frac{1}{\sqrt{2}} \psi_{1,5,1} + \frac{1}{\sqrt{2}} \psi_{3,3,3} \] \[ \phi_3 = \frac{1}{\sqrt{2}} \psi_{1,3,8} + \frac{1}{\sqrt{2}} \psi_{3,8,1} \] \[ \phi_4 = \frac{1}{2} \psi_{3,3,1} + \frac{\sqrt{3}}{2} \psi_{2,4,1} \]
The correct option(s) of reagents and reaction sequences suitable for carrying out the following transformation is/are
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
The correct option with regard to the following statements is
(a) Time-independent Schrödinger equation can be exactly solved for Be\(^{2+}\).
(b) For a particle confined in a one-dimensional box of length \( l \) with infinite potential barriers, the trial variation function \( \phi = \left[ \left( \frac{3}{l^3} \right)^{1/2} x \right] \) is not an acceptable trial wavefunction for \( 0 \le x \le l \).
(c) Wavefunctions for system of Fermions must be anti-symmetric with respect to exchange of any two Fermions in the system.
(d) Born-Oppenheimer approximation can be used to separate the vibrational and rotational motion of a molecule.
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is: