Consider a Carnot engine with a hot source kept at 500 K. From the hot source, 100 J of energy (heat) is withdrawn at 500 K. The cold sink is kept at 300 K. The efficiency of the Carnot engine is ___________ (rounded off to one decimal place).
The efficiency (\( \eta \)) of a Carnot engine is determined solely by the temperatures of the hot and cold reservoirs: \[ \eta = 1 - \frac{T_C}{T_H} \] where \( T_H \) is the absolute temperature of the hot source and \( T_C \) is the absolute temperature of the cold sink. Given: Temperature of the hot source, \( T_H = 500 \) K Temperature of the cold sink, \( T_C = 300 \) K Substitute these values into the formula: \[ \eta = 1 - \frac{300 \, \text{K}}{500 \, \text{K}} = 1 - 0.6 = 0.4 \] The efficiency of the Carnot engine is 0.4. Rounded off to one decimal place, the answer remains 0.4.
The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below.
The slope of the line is \(0.36 \times 10^2\) s, and the y-intercept is \(1.20\) mol\(^{-1}\) L s. The value of the Michaelis constant (\(K_M\)) is ________ \( \times 10^{-3} \) mol L\(^{-1}\) (in integer). [Note: \(v\) is the initial rate, and \([S]_0\) is the substrate concentration]
For the cell reaction, \[ Hg_2Cl_2 (s) + H_2 (1 \, {atm}) \rightarrow 2Hg (l) + 2H^+ (a=1) + 2Cl^- (a=1) \] The standard cell potential is \( \mathcal{E}^0 = 0.2676 \) V, and \( \left(\frac{\partial \mathcal{E}^0}{\partial T}\right)_P = -3.19 \times 10^{-4} \) V K\(^{-1}\). The standard enthalpy change of the reaction (\( \Delta_r H^0 \)) at 298 K is \( -x \) kJ mol\(^{-1}\). The value of \( x \) is ___________ (rounded off to two decimal places). [Given: Faraday constant \( F = 96500 \) C mol\(^{-1}\)]
The mean energy of a molecule having two available energy states at \( \epsilon = 0 \) J and \( \epsilon = 4.14 \times 10^{-21} \) J at 300 K is ___________ \( \times 10^{-21} \) J (rounded off to two decimal places). [Given: Boltzmann constant \( k_B = 1.38 \times 10^{-23} \) J K\(^{-1}\)]
The kinetic energies of an electron (\(e\)) and a proton (\(p\)) are \(E\) and \(3E\), respectively. Given that the mass of a proton is 1836 times that of an electron, the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)) is ___________ (rounded off to two decimal places).
Wavefunctions and energies for a particle confined in a cubic box are \( \psi_{n_x,n_y,n_z} \) and \( E_{n_x,n_y,n_z} \), respectively. The functions \( \phi_1, \phi_2, \phi_3 \), and \( \phi_4 \) are written as linear combinations of \( \psi_{n_x,n_y,n_z} \). Among these functions, the eigenfunction(s) of the Hamiltonian operator for this particle is/are \[ \phi_1 = \frac{1}{\sqrt{2}} \psi_{1,4,1} - \frac{1}{\sqrt{2}} \psi_{2,2,3} \] \[ \phi_2 = \frac{1}{\sqrt{2}} \psi_{1,5,1} + \frac{1}{\sqrt{2}} \psi_{3,3,3} \] \[ \phi_3 = \frac{1}{\sqrt{2}} \psi_{1,3,8} + \frac{1}{\sqrt{2}} \psi_{3,8,1} \] \[ \phi_4 = \frac{1}{2} \psi_{3,3,1} + \frac{\sqrt{3}}{2} \psi_{2,4,1} \]
The correct option(s) of reagents and reaction sequences suitable for carrying out the following transformation is/are
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
The correct option with regard to the following statements is
(a) Time-independent Schrödinger equation can be exactly solved for Be\(^{2+}\).
(b) For a particle confined in a one-dimensional box of length \( l \) with infinite potential barriers, the trial variation function \( \phi = \left[ \left( \frac{3}{l^3} \right)^{1/2} x \right] \) is not an acceptable trial wavefunction for \( 0 \le x \le l \).
(c) Wavefunctions for system of Fermions must be anti-symmetric with respect to exchange of any two Fermions in the system.
(d) Born-Oppenheimer approximation can be used to separate the vibrational and rotational motion of a molecule.
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is: