We are given the vectors:
- \( a = 8b \)
- \( c = -7b \)
The angle between two vectors \( a \) and \( c \) can be found using the formula for the dot product:
\[
\cos \theta = \frac{a \cdot c}{|a| |c|}
\]
First, calculate the dot product \( a \cdot c \). Since \( a = 8b \) and \( c = -7b \), we have:
\[
a \cdot c = (8b) \cdot (-7b) = -56(b \cdot b) = -56|b|^2
\]
Next, calculate the magnitudes of \( a \) and \( c \):
\[
|a| = |8b| = 8|b| \quad \text{and} \quad |c| = |-7b| = 7|b|
\]
Now, substitute these values into the formula for \( \cos \theta \):
\[
\cos \theta = \frac{-56|b|^2}{(8|b|)(7|b|)} = \frac{-56|b|^2}{56|b|^2} = -1
\]
Thus, \( \cos \theta = -1 \), which means:
\[
\theta = \pi
\]
Therefore, the angle between \( a \) and \( c \) is \( \boxed{\pi} \).