\(\text{C}_{4}\text{H}_{10}\)
The given chemical reaction sequence needs to be broken down step-by-step to determine the product [D]. Let's analyze the sequence:
Through these transformations, we identify the correct compound corresponding to option 2, whose structural representation matches the final product obtained at the end of the sequence.
Correct Answer: Option 2 (Ethylbenzene)
The given reaction sequence involves a multi-step transformation beginning with acetaldehyde (CH3CHO) and ending in the formation of an organic compound after a coupling reaction. Let's break it down step-by-step to understand the underlying chemistry and determine the final product [D].
Step 1: The first step is treatment of CH3CHO with lithium aluminium hydride (LiAlH4) followed by hydrolysis with H3O+. This is a well-known reduction step:
CH3CHO (acetaldehyde) → CH3CH2OH (ethanol)
Product [A]: Ethanol
Step 2: Ethanol is treated with concentrated sulfuric acid (H2SO4) under heat (Δ). This is a classic dehydration reaction, where ethanol is converted to ethene:
CH3CH2OH → CH2=CH2 + H2O
Product [B]: Ethene
Step 3: Ethene undergoes addition reaction with HBr, forming bromoethane via electrophilic addition:
CH2=CH2 + HBr → CH3CH2Br
Product [C]: Bromoethane
Step 4: Bromoethane is reacted with bromobenzene in the presence of sodium and dry ether. This is a Wurtz-Fittig reaction — a coupling reaction between an aryl halide and an alkyl halide to form an aryl-alkane:
C6H5Br + CH3CH2Br + 2Na → C6H5CH2CH3 + 2NaBr
Product [D]: Ethylbenzene
Final Answer: The product obtained at the end of this sequence is ethylbenzene, which matches with Option 2 in the given choices.
The order of acidity of the following compounds is:
(i) o-Nitrophenol
(ii) Phenol
(iii) o-Cresol
(iv) Ethanol
Given below are two statements:
Statement I: Dimethyl ether is completely soluble in water. However, diethyl ether is soluble in water to a very small extent.
Statement II: Sodium metal can be used to dry diethyl ether and not ethyl alcohol.
In the light of the given statements, choose the correct answer from the options given below:
A bob of heavy mass \(m\) is suspended by a light string of length \(l\). The bob is given a horizontal velocity \(v_0\) as shown in figure. If the string gets slack at some point P making an angle \( \theta \) from the horizontal, the ratio of the speed \(v\) of the bob at point P to its initial speed \(v_0\) is :
Read More: Alcohols, Phenols, and Ethers