Step 1: Structure of pyrophosphoric acid.
Pyrophosphoric acid contains two phosphate groups (PO₄) joined by an oxygen atom. There are four P-OH bonds (one from each phosphate group) and one P-O-P bond (connecting the two phosphate groups).
Step 2: Analyzing the options.
(A) 3, 1: Incorrect — There are four P-OH bonds, not three.
(B) 4, 1: Correct — There are four P-OH bonds and one P-O-P bond.
(C) 4, 3: Incorrect — There is only one P-O-P bond.
(D) 3, 3: Incorrect — There are four P-OH bonds, not three.
Step 3: Conclusion.
The correct answer is (B) 4, 1.