Question:
Hoffmann bromamide degradation reaction is shown by which of the following?
Hoffmann bromamide degradation reaction is shown by which of the following?
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Hoffmann bromamide degradation is a useful reaction for reducing carbon chain length by one unit while converting an amide into an amine.
Updated On: Mar 14, 2025
- ArNH\(_2\)
- ArCONH\(_2\)
- ArNO\(_2\)
- ArCH\(_2\)NH\(_2\)
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The Correct Option is B
Solution and Explanation
Step 1: Understanding Hoffmann Bromamide Degradation
The Hoffmann bromamide degradation reaction involves the conversion of an amide (\( \text{CONH}_2 \)) to a primary amine (\( \text{NH}_2 \)) with the loss of one carbon atom.
Step 2: Reaction Mechanism
The reaction takes place in the presence of bromine (\( \text{Br}_2 \)) and sodium hydroxide (\( \text{NaOH} \)), leading to the formation of an amine with one less carbon atom.
Step 3: Identifying the Correct Functional Group
The correct starting compound for this reaction is an amide (\( \text{ArCONH}_2 \)), making option (b) ArCONH\(_2\) the correct choice. Final Answer: The Hoffmann bromamide degradation reaction is shown by ArCONH\(_2\).
The Hoffmann bromamide degradation reaction involves the conversion of an amide (\( \text{CONH}_2 \)) to a primary amine (\( \text{NH}_2 \)) with the loss of one carbon atom.
Step 2: Reaction Mechanism
The reaction takes place in the presence of bromine (\( \text{Br}_2 \)) and sodium hydroxide (\( \text{NaOH} \)), leading to the formation of an amine with one less carbon atom.
Step 3: Identifying the Correct Functional Group
The correct starting compound for this reaction is an amide (\( \text{ArCONH}_2 \)), making option (b) ArCONH\(_2\) the correct choice. Final Answer: The Hoffmann bromamide degradation reaction is shown by ArCONH\(_2\).
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