Question:

Heat is supplied at constant pressure to a diatomic gas. The part of this heat that was utilized to increase its internal energy is:

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Understanding the specific heat ratios and how they relate to heat partitioning in gases is crucial in thermodynamics, especially when considering molecular complexity.
Updated On: Mar 19, 2025
  • \( \frac{4}{5} \)
  • \( \frac{5}{7} \)
  • \( \frac{3}{5} \)
  • \( \frac{5}{6} \)
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The Correct Option is B

Solution and Explanation

For a diatomic gas, the heat supplied at constant pressure \( Q \) is related to the change in temperature \( \Delta T \) by:

\[ Q = n C_P \Delta T \]

where:

  • \( n \) is the number of moles of the gas,
  • \( C_P \) is the specific heat at constant pressure.

The total change in internal energy \( \Delta U \) for a diatomic gas is given by:

\[ \Delta U = n C_V \Delta T \]

where \( C_V \) is the specific heat at constant volume.

The relationship between \( C_P \) and \( C_V \) for an ideal gas is:

\[ C_P = C_V + R \]

For a diatomic ideal gas, the ratio \( \gamma = \frac{C_P}{C_V} \) is given by:

\[ \gamma = \frac{7}{5} \]

Thus, we have:

\[ C_P = \frac{7}{5} C_V \]

Now, the part of the heat that increases the internal energy is the heat utilized to increase the temperature at constant volume, which is the change in internal energy. The fraction of the heat supplied that increases internal energy is given by:

\[ \frac{\Delta U}{Q} = \frac{n C_V \Delta T}{n C_P \Delta T} = \frac{C_V}{C_P} = \frac{5}{7} \]

Thus, the fraction of heat utilized to increase the internal energy is \( \frac{5}{7} \).

Therefore, the correct answer is Option (2), \( \frac{5}{7} \).

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