Given below are two statements:
Statement I: Viscosity of liquid decreases with an increase in temperature.
Statement II: The units of viscosity are kg m-1 s-2.
- Viscosity of liquids decreases with increasing temperature.
Step 1: Understanding viscosity behavior
- Viscosity is a measure of a fluid’s resistance to flow.
- As temperature increases, the intermolecular forces weaken, decreasing viscosity.
- This applies to liquids, whereas for gases, viscosity increases with temperature due to molecular kinetic energy increase.
Step 2: Understanding viscosity units
- The SI unit of viscosity is the Pascal-second (Pa·s), which is equivalent to N·s/m2
- This can be written as: Pa·s = kg/m·s
- The given unit (kg m-1 s-2) is incorrect for viscosity but correct for pressure.
The decomposition of a compound A follows first-order kinetics. The concentration of A at time t = 0 is 1.0 mol L-1. After 60 minutes, it reduces to 0.25 mol L-1. What is the initial rate of the reaction at t = 0? (Take ln 2 = 0.693)