Statement I: Ammonium carbonate (NH4)2CO3 is basic in solution because it forms a weak acid (NH4+) and a weak base (CO32-). The carbonate ion (CO32-) can accept protons, making the solution basic.
Statement II: This statement is also correct as the pH of a salt solution formed from a weak acid and a weak base depends on the relative values of Ka and Kb.
So, Statement I and II both are correct.