Let's evaluate the given statements:
- Assertion (A): A catalyst generally increases the rate of a reaction. This is correct. A catalyst increases the rate of a reaction by providing an alternative reaction pathway, allowing the reaction to proceed faster.
- Reason (R): It lowers the activation energy of a reaction by providing a new path. This is also correct. The primary mechanism by which a catalyst increases the reaction rate is by lowering the activation energy, which is the energy barrier that reactants must overcome to form products.
Now, we need to determine if (R) is the correct explanation of (A). Since a catalyst increases the reaction rate precisely because it lowers the activation energy (as stated in R), the reason directly explains the assertion. Therefore, both (A) and (R) are correct, and (R) is the correct explanation of (A).
So, the correct answer is Both (A) and (R) are correct and (R) is the correct explanation of (A).